Crystallographic report: Bis[tri(o-chlorobenzyl)tin(IV)] piperazinylbisdithiocarbamate
β Scribed by Handong Yin; Chuanhua Wang
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 79 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.586
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β¦ Synopsis
The centrosymmetric structure of (o-C 6 H 4 CH 2 ) 3 SnS 2 CN(CH 2 CH 2 ) 2 NCS 2 Sn(CH 2 C 6 H 4 -o) 3 features chelating dithiocarbamate ligands, so that a trigonal bipyramidal C 3 S 2 coordination geometry for tin results.
π SIMILAR VOLUMES
The tin atom in (2-Cl-C 6 H 4 CH 2 ) 2 Sn(Cl)S 2 CN(CH 2 CH 2 ) 2 NCH 3 is in a trigonal bipyramid geometry defined by a C 2 ClS 2 donor set with the chlorine and weakly bound sulfur atoms in axial positions.
## Abstract The centrosymmetric structure of bis[tris(2βmethylβ2βphenylpropyl)tin]piperazinyldithiocarbamate contains fourβcoordinated tin and monodentate dithiocarbamate ligands. Copyright Β© 2004 John Wiley & Sons, Ltd.
## Abstract The crystal structure of [(__p__βCH~3~C~6~H~4~)~3~GeCH(__o__βCH~3~C~6~H~4~)CH~2~CO~2~]~2~Sn(C~4~H~9~)~2~ consists of a monomer with the atoms of tin and germanium both occupying tetrahedral geometries. However, the tin atom is distorted towards a skew trapezoidal bipyramid geometry as a