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Crystallographic report: Chlorodi(o-chlorobenzyl)tin N-methylpiperazinyldithiocarbamate

โœ Scribed by Han-Dong Yin; Sheng-Cai Xue

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
70 KB
Volume
19
Category
Article
ISSN
0268-2605

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โœฆ Synopsis

The tin atom in (2-Cl-C 6 H 4 CH 2 ) 2 Sn(Cl)S 2 CN(CH 2 CH 2 ) 2 NCH 3 is in a trigonal bipyramid geometry defined by a C 2 ClS 2 donor set with the chlorine and weakly bound sulfur atoms in axial positions.

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Crystallographic report: Bis[tri(o-chlor
Crystallographic report: Bis[tri(o-chlorobenzyl)tin(IV)] piperazinylbisdithiocarbamate
โœ Handong Yin; Chuanhua Wang ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 79 KB ๐Ÿ‘ 1 views

The centrosymmetric structure of (o-C 6 H 4 CH 2 ) 3 SnS 2 CN(CH 2 CH 2 ) 2 NCS 2 Sn(CH 2 C 6 H 4 -o) 3 features chelating dithiocarbamate ligands, so that a trigonal bipyramidal C 3 S 2 coordination geometry for tin results.