Crystallographic report: Bis[tris(2-methyl-2-phenylpropyl)tin] piperazinyldithiocarbamate
β Scribed by Laijin Tian; Zhicai Shang; Qingsen Yu; Daixi Li; Guoming Yang
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 83 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.600
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β¦ Synopsis
Abstract
The centrosymmetric structure of bis[tris(2βmethylβ2βphenylpropyl)tin]piperazinyldithiocarbamate contains fourβcoordinated tin and monodentate dithiocarbamate ligands. Copyright Β© 2004 John Wiley & Sons, Ltd.
π SIMILAR VOLUMES
In the dinuclear molecule of [(C 5 H 4 N) 3 N] 2 CdCl 2 CdCl 2 , one cadmium is octahedrally coordinated by a Cl 2 N 4 donor set and the other cadmium is tetrahedrally coordinated by four chlorine atoms. The dinuclear units are connected by Ο -Ο interactions to give a two-dimensional network.
The dinuclear molecule of p-{[(Me 3 Si) 2 CH]Sn(Cl) 2 CH 2 SiMe 2 } 2 C 6 H 4 is centrosymmetric and adopts an `S' conformation that is stabilized by intramolecular CΓHΓΓΓp interactions. The tin atom exists within a distorted tetrahedron defined by a C 2 Cl 2 donor set.