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Crystallographic report: Bis(3-methyl-2-cyclopenten-1-one)dichloro-oxovanadium(IV)

✍ Scribed by Jan Honzíček; Ivana Císařová; Jaromír Vinklárek


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
97 KB
Volume
19
Category
Article
ISSN
0268-2605

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✍ Dainis Dakternieks; Bernhard Zobel; Edward R. T. Tiekink 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 100 KB 👁 1 views

The dinuclear molecule of p-{[(Me 3 Si) 2 CH]Sn(Cl) 2 CH 2 SiMe 2 } 2 C 6 H 4 is centrosymmetric and adopts an `S' conformation that is stabilized by intramolecular CÐHÁÁÁp interactions. The tin atom exists within a distorted tetrahedron defined by a C 2 Cl 2 donor set.