Crystallographic report: Crystal and molecular structure of tetramethylammoniumdiisothiocyanatotriphenyltin(IV), [NMe4SnPh3(NCS)2]
✍ Scribed by Kochikpa Y. A. Okio; Libasse Diop; Aliou H. Barry; Tahar Jouini; Simòn H. Ortega
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 92 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.437
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✦ Synopsis
Abstract
The structure of NMe~4~SnPh~3~(NCS)~2~ is molecular, without any significant intermolecular contacts in the lattice. The trigonal plane around the tin atom is defined by three carbon atoms from the phenyl groups and the axial positions occupied by the NCS groups. Copyright © 2003 John Wiley & Sons, Ltd.
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catena-Bis(1,2-diaminoethane)nickel(II)-µ-dicyanoargentate]-dicyanoargentate, [Ni(en) 2 Ag 2 (CN) 4 ], was synthesized and its chain-like crystal structure was determined by X-ray crystal analysis.
## Abstract A two‐dimensional layer structure is found in the title compound comprising interconnected 22‐membered rings and __trans__‐C~3~O~2~ trigonal bipyramidal coordination geometries for tin. Copyright © 2003 John Wiley & Sons, Ltd.