Crystallographic report: The crystal structure of bis(η5-cyclopentadienyl)- diazido-vanadium(IV)
✍ Scribed by Jan Honzíček; Milan Erben; Ivana Císařová; Jaromír Vinklárek
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 107 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.762
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## Abstract A two‐dimensional layer structure is found in the title compound comprising interconnected 22‐membered rings and __trans__‐C~3~O~2~ trigonal bipyramidal coordination geometries for tin. Copyright © 2003 John Wiley & Sons, Ltd.
The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4