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Crystallographic report: Chain-like crystal structure of [Ni(en)2Ag(CN)2] [Ag(CN)2]

✍ Scribed by Yan-Pin Ren; La-Sheng Long; Rong-Bin Huang; Lan-Sun Zheng


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
184 KB
Volume
19
Category
Article
ISSN
0268-2605

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✦ Synopsis


catena-Bis(1,2-diaminoethane)nickel(II)-µ-dicyanoargentate]-dicyanoargentate, [Ni(en) 2 Ag 2 (CN) 4 ], was synthesized and its chain-like crystal structure was determined by X-ray crystal analysis.


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## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Single‐crystal X‐ray analyses indicate that the CB~11~I~5~Br~6~^2−^ dianion has a signi