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Crystallographic report: a double chain coordination polymer: {[Zn(H2O)6][Zn(3,3′,4,4′-benzophenonetetracarboxylate)H2O]·4H2O}n

✍ Scribed by Yang-Yi Yang; Lap Szeto; Wing-Tak Wong

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
147 KB
Volume
17
Category
Article
ISSN
0268-2605

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✦ Synopsis

The double-chain coordination polymer, {[Zn(H 2 O) 6 ][Zn(bbtc)H 2 O]•4H 2 O} n (bbtc = 3, 3 , 4, 4benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three bbtc ligands, and a water molecule, forming a geometry intermediate between square-pyramidal and trigonal bipyramidal.

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