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[Zn2(thf)2(EtZn)6Zn4(μ4-O)(tBuPO3)8]: A Dodecanuclear Zincophosphonate Aggregate with a Zn4(μ4-O) Core

✍ Scribed by Yu Yang; Jiri Pinkas; Mathias Noltemeyer; Hans-Georg Schmidt; Herbert W. Roesky

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
108 KB
Volume
38
Category
Article
ISSN
0044-8249

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Crystallographic report: a double chain coordination polymer: {[Zn(H2O)6][Zn(3,3′,4,4′-benzophenonetetracarboxylate)H2O]·4H2O}n
✍ Yang-Yi Yang; Lap Szeto; Wing-Tak Wong 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 147 KB 👁 1 views

The double-chain coordination polymer, {[Zn(H 2 O) 6 ][Zn(bbtc)H 2 O]•4H 2 O} n (bbtc = 3, 3 , 4, 4benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three b