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ChemInform Abstract: Synthesis and Structure of [Zn6(H2O)8(HPO4)4 (HPO3O)4] ×2H2N2C6H16.

✍ Scribed by P. REINERT; A. KHATYR; B. MARLER; J. PATARIN

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 structure structure (solids and liquids) D 2000

24 -013

Synthesis and Structure of [Zn 6 (H 2 O) 8 (HPO 4 ) 4 (HPO

-A new two-dimensional zincophosphate is synthesized from a zincophosphate solution in the presence of tetramethylethylenediamine. The structure is monoclinic (space group P2 1 /c, Z = 1) and consists of parallel [Zn 6 (H 2 O) 8 (HPO 4 ) 4 (HPO 3 O) 4 ] 4-sheets separated by TMEDA cations (single crystal XRD). The layers display 4-and 8-nonplanar membered rings. A poor thermal stability is observed.

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