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Crystallographic observation of a trapped tetrahedral intermediate in a metalloenzyme

✍ Scribed by Wilson, David K. ;Quiocho, Florante A.

Book ID
109965176
Publisher
Nature Publishing Group
Year
1994
Tongue
English
Weight
465 KB
Volume
1
Category
Article
ISSN
1545-9993

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πŸ“œ SIMILAR VOLUMES

Direct observation of a tetrahedral inte
Direct observation of a tetrahedral intermediate during amidine hydrolysis
✍ Dwight R. Robinson πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 204 KB

Recent experiments have led to the conclusion that the hydrolysis of the formamidinium compound, diphenylimidazolinium chloride (I, R = C6H5) proceeds through the rate determining decomposition of a tetrahedral intermediate (III) according to the mechanism of eq.1 (2).