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Reactivity of a tetrahedral intermediate in hydrolysis of N-acetylpyrrole

โœ Scribed by Antonio Cipiciani; Gianfranco Savelli; Clifford A. Bunton

Book ID
112127528
Publisher
Journal of Heterocyclic Chemistry
Year
1984
Tongue
English
Weight
139 KB
Volume
21
Category
Article
ISSN
0022-152X

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๐Ÿ“œ SIMILAR VOLUMES

Direct observation of a tetrahedral inte
Direct observation of a tetrahedral intermediate during amidine hydrolysis
โœ Dwight R. Robinson ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

Recent experiments have led to the conclusion that the hydrolysis of the formamidinium compound, diphenylimidazolinium chloride (I, R = C6H5) proceeds through the rate determining decomposition of a tetrahedral intermediate (III) according to the mechanism of eq.1 (2).