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Crystallographic and NMR Studies on Chiral Palladium(II) Allyl Ferrocene-Based P,N Complexes

✍ Scribed by Burckhardt, Urs; Gramlich, Volker; Hofmann, Patrick; Nesper, Reinhard; Pregosin, Paul S.; Salzmann, Renzo; Togni, Antonio


Book ID
126954915
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
438 KB
Volume
15
Category
Article
ISSN
0276-7333

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Novel cationic allylpalladium(II) complexes containing the alkaloid (-)-sparteine (1) as a bidentate ligand have been prepared. Two of them, [q3-(cyclohex-2-enyl)] (sparteine)palladium(II) hexafluorophosphate ([Pd(v3-C6H,)(sparteine)][PF6]; 3b) and (sparteine)[~3-(1,1,3-triphenylallyl)]palladium(II)