NMR Studies of Chiral P,S-Chelate Platinum, Rhodium, and Iridium Complexes and the X-ray Structure of a Palladium(II) Allyl Derivative
✍ Scribed by Albinati, Alberto; Eckert, Jürgen; Pregosin, Paul; Rüegger, Heinz; Salzmann, Renzo; Stössel, Corinna
- Book ID
- 120591529
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 451 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
Novel cationic allylpalladium(II) complexes containing the alkaloid (-)-sparteine (1) as a bidentate ligand have been prepared. Two of them, [q3-(cyclohex-2-enyl)] (sparteine)palladium(II) hexafluorophosphate ([Pd(v3-C6H,)(sparteine)][PF6]; 3b) and (sparteine)[~3-(1,1,3-triphenylallyl)]palladium(II)
H-and 13C-NMR. data are reported for the complexes [Pt (1)Ll and [Pt (2)Ll; hexyl), DMSO, pyridine, secondary amine. The molecular structures of [Pt(2) (NHEt,)] (I) and [Pt (2)(PPh3)] (11) have been determined by X-ray analysis.