31P, 13C, and 1H NMR Studies on Chiral Allyl Ferrocenyldiphosphine Complexes of Palladium(II)
โ Scribed by Pregosin, Paul S.; Salzmann, Renzo; Togni, Antonio
- Book ID
- 121361699
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 653 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0276-7333
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## Abstract The chiral (ฯโallyl)Pd(II) complex [Pd(ฮท^3^๏ฃฟCH~3~CHCHCH~2~)(__S, S__โChiraphos)]CF~3~SO~3~ was shown to exist in four isomeric forms (two diastereomeric and two geometric). Aspects of their threeโdimensional structures were elucidated using ^1^H, ^13^C and ^31^P oneโ and twoโdimensional
The chiral macrocyclic complexes obtained in a template condensation of (R,R)-1,2-diaminocyclohexane and 2,6-diformylpyridine, Ln \ La(III), Ce(III), Eu(III) and Yb(III), were studied by 1H [LnL](NO 3 ) 3 , and 13C NMR spectroscopy. The signal assignment was based on COSY, NOESY and HMQC measurement