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Crystallization of ultraphosphates via the gas phase. The crystal structures of FeP4O11, ZnP4O11 and CdP4O11

โœ Scribed by M. Weil; R. Glaum

Book ID
104372699
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
729 KB
Volume
35
Category
Article
ISSN
0992-4361

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Source of material: Synthesis from acidic melt of P2O5, H1PO4 and cobalt hydroxide carbonate at about 673 K. This structure is isomorphous to magnesium and zinc ultraphosphate (see refs. 1 and 2). Monoclinic, P12i/cl (No. 14), a = 5.320(1 ) ร‚, b = 22.263(2) ร€, c = 7.408(1 ) ร‚, รŸ = 110.070(9)ยฐ, V = 8