Crystal structures of copper(II) complexes with methyliminodiacetate ions and 1,10-phenanthroline or imidazole [Cu(Phen)H2O][Cu(Mida)2]·2H2O and [Cu(Mida)Im]
✍ Scribed by M. Zabel; A. L. Poznyak; V. I. Pawlowski
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2005
- Tongue
- English
- Weight
- 116 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-4766
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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
The title compound [Cu 2 (phen) 2 (C 9 H 14 O 4 ) 2 ] 6 H 2 O was prepared by the reaction of CuCl 2 ´2 H 2 O, 1,10phenanthroline (phen), azelaic acid and Na 2 CO 3 in a CH 3 OH/H 2 O solution. The crystal structure (monoclinic, C2/c (no. 15), a = 22.346(3), b = 11.862(1), c = 17.989(3) A Ê , b = 91