Crystal Structures, Electronic Properties, and Pressure-Induced Superconductivity of the Tetrahedral Cluster Compounds GaNb 4 S 8 , GaNb 4 Se 8 , and GaTa 4 Se 8
β Scribed by Pocha, Regina; Johrendt, Dirk; Ni, Bingfang; Abd-Elmeguid, Mohsen M.
- Book ID
- 125852323
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 346 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
New tetrahedral metal cluster compounds were synthesized and characterized by means of single crystal Xray methods. GeV 4 S 8 (F43m, Z = 4, a = 9.655(1) A Γ ) and GeV 4 S 8 (a = 10.139(1) A Γ ) crystallize in the GaMo 4 S 8 -structure, built up by cubane-like (V 4 S 4 ) 4+ and tetrahedral (GeS 4 ) 4
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