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Crystal structure of the new ternary uranium germanide UNi5Ge3 and magnetic properties of UNi5X3 (X=Ge, Si)

✍ Scribed by A Perricone; H Noël

Book ID
117621138
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
295 KB
Volume
346
Category
Article
ISSN
0925-8388

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New compounds with the formula U 3 TiX 5 have been synthesized for X ‫؍‬ Ge, Sn. The crystal structure of U 3 TiGe 5 has been re5ned from single crystal X-ray di4raction data to R(F) ‫؍‬ 0.032, R w ‫؍‬ 0.037, and was found to crystallize with the hexagonal U 3 TiSb 5 structure type, with a ‫؍‬ 8.495

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Crystal and Magnetic Structure of the Binary Uranium Germanide U 3 Ge 5 . -The title compound is prepared by arc melting of the elements under reduced pressure followed by annealing at different temperatures (1200-900 • C). U 3 Ge 5 crystallizes in the hexagonal AlB 2 type structure (space group P6