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Crystal structure of the new borate Li3Gd(BO3)2. Comparison with the homologous Na3Ln(BO3)2 (Ln: La, Nd) compounds

✍ Scribed by Veronique Jubera; Pierre Gravereau; Jean Pierre Chaminade

Book ID
114370374
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
777 KB
Volume
3
Category
Article
ISSN
1293-2558

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Crystal Structure of Sodium Rare Earth O
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A new structural family of rare earth oxyborates Na 2 Ln 2 (BO 3 ) 2 O (Ln ‫؍‬ Sm, Eu and Gd) is evidenced. The structure, determined by single crystal X-ray diffraction, is monoclinic, space group P2 1 /c, Z ‫؍‬ 4, with a ‫؍‬ 10.695(6) A s , b ‫؍‬ 6.320(4) A s , c ‫؍‬ 10.328(6) A s , ‫؍‬ 117.80(4)Β°