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Crystal structure of hexacyano cobaltate(III) of caesium and tetramethylammonium: Cs[(Me)4N]2Co(CN)6

✍ Scribed by Angel Dago Morales; René Guardiola Romero; Julio Duque Rodríguez; Ramόn Pomés Hernández; José Fernández Bertrán

Publisher
Springer
Year
1990
Tongue
English
Weight
211 KB
Volume
15
Category
Article
ISSN
0340-4285

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Metathesis Reactions of the super-Prussian Blue Systems [(Me3Sn)3M(CN)6] (M=Co, Ir) with, inter alia, Tetrapropylammonium (and -phosphonium) Ions: Crystal Structures of [(nPr4P)(Me3Sn)2Co(CN)6·2H2O] and [(nPr4N)(Me3Sn)2Ir(CN)6·2H2O]
✍ Eyck-Michael Poll; Falk Olbrich; Sabine Samba; R. Dieter Fischer; Paolo Avalle; 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 609 KB

Tetrapropylammonium and -phosphonium ions, nPr 4 E ؉ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]