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Novel Low Dimensional Cluster Compounds: Syntheses and Crystal Structures of Cs[{Me3Sn}3{Re6Se8(CN)6}], [{Me3Sn(H2O)}2{Me3Sn}{Re6Se8(CN)6}]

✍ Scribed by Maria S. Tarasenko; Alexandra Yu. Ledneva; Nikolai G. Naumov; Dmitry Y. Naumov; Vladimir E. Fedorov

Publisher
Springer
Year
2005
Tongue
English
Weight
397 KB
Volume
16
Category
Article
ISSN
1040-7278

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Tetrapropylammonium and -phosphonium ions, nPr 4 E Ψ‰ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]