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Crystal structure of potassium tetramethylammonium hexacyanocobaltate(III) trihydrate: K3(Me4N)3[Co(CN)6]2·3H2O

✍ Scribed by René Guardiola Romero; Angel Dago Morales; Julio Duque Rodríguez; José Fernández Bertrán

Publisher
Springer
Year
1992
Tongue
English
Weight
211 KB
Volume
17
Category
Article
ISSN
0340-4285

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✍ Eyck-Michael Poll; Falk Olbrich; Sabine Samba; R. Dieter Fischer; Paolo Avalle; 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 609 KB

Tetrapropylammonium and -phosphonium ions, nPr 4 E ؉ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]