Crystal Structure of 3-Phenyl-4-Tosylimino-1,3-Thiazetidine-2-thione
✍ Scribed by Geoffrey S. D. King; Luc van Meervelt; Gerrit L'abbé
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 113 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0037-9646
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## Abstract The title compound 1 can be transformed into functionalized 5‐ and 6‐ membered heterocycles by treatment with nucleophilic reagents. For instance, the reaction of 1 with tert‐butyl isonitrile yields the two isomers 2 and 3, resulting from different positions of attack at the 4‐membered
The crystal structure of 4-tert-butylimino-3,3-diethoxycarbonyl- I-methyl-2-tosylimino-azecidine ( C H N 0 S, a = 2 5 . 3 3 4 ( 4 ) , b = 8.223(1), c = 11.574(2) 1, f? = 91.88(1)', space group PZ1/n, Z = 4) has been determined by single-crystal X-Ray diffraction techniques and refined to R = 0.095 (
The title compound (C 15 H 12 N 3 OSCl) crystallizes in the monoclinic space group P2 1 /n with a = 11.211( 3), b = 8.106(2), c = 17.494(4) Å, β = 104.49(2)º, V = 1539.2(7) Å 3 , Z = 4, D cal = 1.371 Mg/m 3 at T = 293 K. The structure was solved by direct methods and refined by full-matrix least-squ