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Synthesis of heterocycles from 3-phenyl-4-tosylimino-1, 3-thiazetidine-2-thione

✍ Scribed by Gerrit L'abbé; Patricia Vangheluwe; Suzanne Toppet

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
274 KB
Volume
92
Category
Article
ISSN
0037-9646

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Ring Transformations of 3-Phenyl-4-Tosyl
Ring Transformations of 3-Phenyl-4-Tosylimino-1, 3-Thiazetidine-2-One
✍ Gerrit L'abbé; Jean-Paul Dekerk; Martine Deketele 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 252 KB

## Abstract The title compound 1 can be transformed into functionalized 5‐ and 6‐ membered heterocycles by treatment with nucleophilic reagents. For instance, the reaction of 1 with tert‐butyl isonitrile yields the two isomers 2 and 3, resulting from different positions of attack at the 4‐membered