The crystal structure of 4-tert-butylimino-3,3-diethoxycarbonyl- I-methyl-2-tosylimino-azecidine ( C H N 0 S, a = 2 5 . 3 3 4 ( 4 ) , b = 8.223(1), c = 11.574(2) 1, f? = 91.88(1)', space group PZ1/n, Z = 4) has been determined by single-crystal X-Ray diffraction techniques and refined to R = 0.095 (
✦ LIBER ✦
Crystal Structure of 2-Phenyl-4-Tert-Butyl-5-Tert-Butylimino-Δ2-1,3,4-Oxadiazolium Picrate
✍ Scribed by Geoffrey S. D. King; Luc van Meervelt; Gerrit L'abbé
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 120 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0037-9646
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✦ Synopsis
Oxidative cyclization of N-monosubstituted-N'-carboalkoxyguanidines 1 furnish either 1,2,4oxadiazoles 2 or I ,3,4-oxadiazoles 3.1*2 the latter resulting from rearrangement of the elusive N-carboalkoxy substituted diaziridinimines.
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