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Crystal and Molecular Structure of (Tri-tert-butyl-η5-cyclopentadienyl)-(1,2,4-tri-tert-butyl-η3-cyclopentenyl)nickel

✍ Scribed by Schneider, JöRg J. ;Krüger, Carl


Publisher
Wiley (John Wiley & Sons)
Year
1992
Tongue
English
Weight
265 KB
Volume
125
Category
Article
ISSN
0009-2940

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✦ Synopsis


Metal vaporization 1 q5-q3-Sandwich compound 1 Slipped sandwich structure Nickel sandwich complex (Tri-tert-butyl-q5-cyclopentadienyl)(1,2,4-tri-tert-butyl-q3-cy-membered rings. Its 13C-NMR data are reported together with clopenteny1)nickel (1) is accessible by the metal vapor route. data on (tert-butyl-q5-cyclopentadienyl)(tert-butyl-~3-cyclo-The molecule adopts a slipped sandwich structure in the solid penteny1)nickel 2 and (di-tert-b~tyl-~~-cyclopentadienyl)(distate with the nickel atom q5-q3-coordinated to the fivetert-butyl-q3-cyclopenteny1)nickel 3.


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