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Crystal structure and electrical conductivity of N-methylquinolinium bis(1,3-dithiole-2-thione-4,5-dithiolato)nickelate(III)

✍ Scribed by J.P. Cornelissen; E.J. Creyghton; R.A.G. de Graaff; J.G. Haasnoot; J. Reedijk


Book ID
108323905
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
516 KB
Volume
185
Category
Article
ISSN
0020-1693

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In the title ion-pair compound, (C 12 H 11 FN)[Ni(C 3 S 5 ) 2 ], the Ni III atom is coordinated by four sulfur atoms of the two 2thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry. Weak C-HÁ Á ÁS interactions are found, resulting in a three-dimensional supramolecular network.