The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.
Crystal and molecular structures of di-µ-azido-bis-[N,N,N′,N′-tetramethylethylenediamine azido copper(II)]
✍ Scribed by Itka Bkouche-Waksman; Sonia Sikorav; Olivier Kahn
- Publisher
- Springer
- Year
- 1983
- Tongue
- English
- Weight
- 363 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1572-8854
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II
The title complex, [Cu 2 (N 3 ) 2 (C 12 H 16 N 3 O 3 ) 2 ], is an azidebridged dinuclear copper(II) complex. There is a crystallographic inversion centre at the mid-point of the CuÁ Á ÁCu vector. Each Cu atom is coordinated by one O and two N atoms of one Schiff base ligand and two bridging N atoms