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Crystal and molecular structure of lycorine-chlorohydrin: Revision of the stereochemistry

✍ Scribed by Jun Toda; Takehiro Sano; Yoshisuke Tsuda; Miyuki Kaneda; Yoichi Iitaka

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
128 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

Action of POCls and HCl on 1-0-acetyllycorine gave, quantitatively, O-acetyllycorine-chlorohydrin, which was convertible, in good yield, to lycorene-a-oxide and so-called lycorine-cis-chlorohydrin.

The configuration of the latter compound was revised establishing as tram by a single crystal X-ray analysis.

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