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Crystal and molecular structure of an iron complex containing both 1,1-dithiolato and 1,2-dithiolene ligands, bis(N, N-diethyldithiocarbamato) [cis-1,2-bis(trifluoromethyl)ethylene-1,2-dithiolato]iron

✍ Scribed by Horrocks, William D.; Johnston, Donald L.; Rohrbaugh, Wayne L.


Book ID
127310788
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
814 KB
Volume
10
Category
Article
ISSN
0020-1669

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The title compounds were prepared from 1,3,4,6tetrathiapentalene-2,5-dione (1) in one step via the in situ The X-ray single crystal structure of (Et 4 N) 2 [Zn(dmid) 2 ] (3 a) gave the tetragonal space group P4 3 2 1 2 with a = b = 13.810(2) A Ê , c = 16.480(3) A Ê , and Z = 4. (n-Bu 4 N) 2 [Zn(dmi