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Crystal and molecular structure and the absolute configuration of N-phenyl-N′-(1-phenylethyl)methanephosphonodiamidate

✍ Scribed by Michał W. Wieczorek; Jarosław Błaszczyk; Bożenna Krzyżanowska

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
274 KB
Volume
4
Category
Article
ISSN
1042-7163

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✦ Synopsis

The structural investigation of the product of the reaction of methanephosphonodichloridate with R( +)-I-phenylethylamine and aniline in the presence of triethylamine [3] was performed. The obtained compound Cl5H1d2OP (1) crystallizes in monqclinic system, sgace group P2, with a = 10.466(1) A, b = 6.984(3) A, c = 10.471(2) A, / 3 = 95.43(1)", V = 762.0(9) A3. Z = 2, and R = 0.037. The absolute configuration at the P and C8 atoms was determined by means of X-ray crystallography as Rp and RcBr respectively.

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