The structural investigation of the product of the reaction of methanephosphonodichloridate with R( +)-I-phenylethylamine and aniline in the presence of triethylamine [3] was performed. The obtained compound Cl5H1d2OP (1) crystallizes in monqclinic system, sgace group P2, with a = 10.466(1) A, b = 6
Crystal and molecular structures and the absolute configuration of O,Se-dimethyl-N-(1-phenylethyl)phosphoramidoselenoates
✍ Scribed by Michał W. Wieczorek; Jarosław Błaszczyk; Bożenna Krzyżanowska
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 337 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1042-7163
No coin nor oath required. For personal study only.
✦ Synopsis
The structural investigation of two enantiomers of the phosphoroorganic selenium-containing compound [(+)C,fl,dzI02PSe (1) and (-)CIflI,N02PSe (l')] was carried out. The absolute configuration at the P and C3 atoms was found to be R for compound 1 and, respectively, S for compound 1'.
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