𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Crystal and molecular structure of N-(Diethylaminothiocarbonyl)-N′-phenyl-benzamidine

✍ Scribed by Dr. U. Braun; J. Sieler; R. Richter; I. Leban; L. Golič

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
271 KB
Volume
23
Category
Article
ISSN
0232-1300

No coin nor oath required. For personal study only.

✦ Synopsis

Crystal and Molecular Structure of N-(Diethylaminothiocarbonyl) -N -phenyl-benzamidine Dedicated to Professor Hermann NEELS on the occasion of his 75th birthday The crystal structure of the title compound has been determined by X-ray diffractometer data collected on a CAD-4 diffractometer. C1,H21N,S crystallizes monoclinic, space group P 2Jn with a = 8.939(1) A, b = 18.992(3) A, c = 10.416(2) A, j3 = 97.29(2) A and Z = 4. Least-squares refinement gave a value of R = 0.107 for 2647 observed reflections. The molecule has a configuration which can be described best by Z, E' and exists in the tautomeric enamine form. The molecules form infinite chains connected by intermolecular N-H ... S interactions, with H ... S distances of 2.46 A. Die Kristallstruktur der Titelverbindung wurde durch Rontgenstrukturanalyse bestimmt. Die Daten wurden mit einem CAD-4 Diffraktometer gesammelt. Cl,H,,N,S kristallisiert monoklin in der Raumgruppe P 2,/n mit a = 8,939(1) A, b = 18,992(3) A, c = 10,416(2) A, j3 = 97,29(2)' und Z = 4. Die Verfeinerung nach der Methode der kleinsten Fehlerquadrate ergab einen R-Wert von 0,107 fur 2647 beobachtete Reflexe. Das Molekul besitzt eine Konfiguration, die a m besten mit Z, E' beschrieben werden kann und liegt in der tautomeren Enamin-Form vor. Die Molekule bilden unendliche Ketten, die

📜 SIMILAR VOLUMES

Crystal and molecular structure and the
Crystal and molecular structure and the absolute configuration of N-phenyl-N′-(1-phenylethyl)methanephosphonodiamidate
✍ Michał W. Wieczorek; Jarosław Błaszczyk; Bożenna Krzyżanowska 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB 👁 1 views

The structural investigation of the product of the reaction of methanephosphonodichloridate with R( +)-I-phenylethylamine and aniline in the presence of triethylamine [3] was performed. The obtained compound Cl5H1d2OP (1) crystallizes in monqclinic system, sgace group P2, with a = 10.466(1) A, b = 6

Synthesis, Molecular and Crystal Structu
Synthesis, Molecular and Crystal Structure of Two Tricyclic N-Aminoimides.
✍ M. Struga; B. Miroslaw; I. Wawrzycka-Gorczyca; J. Kossakowski; A. E. Koziol 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 18 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.