The velocity dependence of the excitation of mercury to Hg(6 3Pr) by CO(a31$ was determined in a cross beam esperiment by measuring the time-of-flight distribution of both the metastable CO molecules and the mercury 2537 A emission. Fcr a cross section functional dependence of u-'\*, n was found to
Crossed molecular beam study of electronic energy transfer: Hg(63P2) + NO(X2Π) → NO(A2Σ) + Hg(61S0)
✍ Scribed by H.F. Krause; S. Datz
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 453 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Near resonant electronic energy transfer in the reaction Hg(6 3Pa) + NO(X *lI) -, NO(A * E) + Hg(6 'SO) ha? jeen investigated in a thermal ener,g crossed beam experiment. The most probable rotational state in the product, NO(A 2 Z), exceeds that of the reactant, NO(X2tl), by = 3 rotational levels for molecular beam temperature in the range 100-400 K.
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The formation of NO (A,v) and NO(B,v) was investigated from the reaction Co(a,v') + NO(X,v" -0) in a beam-beam configuration. The nascent rovibrational distributions of NO(A,v-0-2) and NO(B,v-0-2) were determined from NO(A ~ X) and NO(B ~ X) emissions by means of spectral simulation. The branching r
The energy transfer reaction of metastable N2(a lI-Ig, v') prepared by a dc discharge of high-purity nitrogen with CO(X 1E, v" = 0) was investigated by measuring the vacuum ultraviolet emission spectra of the electronically excited species CO(A 11-1, v') and NE(a lIIg, v') during the collision perio