✦ LIBER ✦

Molecular beam time-of-flight sensitized fluorescence: the velocity dependence of CO(a3Π) + Hg(61S0) → CO(X1Σ+) + Hg(63P 1)

✍ Scribed by F.J. van Itallie; R.M. Martin

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 481 KB
Volume: 17
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)87120-3

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✦ Synopsis

The velocity dependence of the excitation of mercury to Hg(6 3Pr) by CO(a31$ was determined in a cross beam esperiment by measuring the time-of-flight distribution of both the metastable CO molecules and the mercury 2537 A emission. Fcr a cross section functional dependence of u-'*, n was found to be 0.8 * 0.1 over the relative velocity range u = 300-700 m/set.

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