Near resonant electronic energy transfer in the reaction Hg(6 3Pa) + NO(X \*lI) -, NO(A \* E) + Hg(6 'SO) ha? jeen investigated in a thermal ener,g crossed beam experiment. The most probable rotational state in the product, NO(A 2 Z), exceeds that of the reactant, NO(X2tl), by = 3 rotational levels
✦ LIBER ✦
A crossed beam study of the single-charge transfer process Hg2+(1S) + Kr(1S) → Hg+(2S) + Kr+ (2P32, 2P12) AT eV collision energies
✍ Scribed by Brētislav Friedrich; Jan Vančura; Martin Sadílek; Zdenek Herman
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 285 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0009-2614
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Two theoretical models, a reorganization model and an activation model, are presented for accurately determining the energy barrier of the type Ž . 2qr3q M H O of the transition-metal complexes in the electron-transfer process. Ab initio 2 6 Ž . 2qr3q calculations are carried out at UMP2r6-311G leve