## Abstract The structural development of polystyrene, which was crosslinked with varying amounts of the multifunctional cluster Zr~6~O~4~(OH)~4~(methacrylate)~12~, was followed in situ by smallβangle Xβray scattering at a synchrotron radiation source. It was observed that crazing strongly diminish
β¦ LIBER β¦
Crazing studies of polystyrene. I. A new phenomenological observation
β Scribed by J. F. Fellers; B. F. Kee
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 536 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
This paper reports a new phenomenological observation regarding the stress crazing of glassy polystyrene. It was found that the applied stress to initiate a craze, often called the critical crazing stress, is independent of molecular weight. Further, the gross structure of the craze does depend on molecular weight, and other phenomenological aspects previously reported have been reaffirmed. These observations are interpreted in the light of knowledge from the literature and provide a better understanding of the crazing process.
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