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Cover Picture: Multicenter Strategy for the Development of Catalytic Enantioselective Nucleophilic Alkylation of Ketones: Me2Zn Addition to α-Ketoesters (Angew. Chem. Int. Ed. 44/2003)

✍ Scribed by Ken Funabashi; Markus Jachmann; Motomu Kanai; Masakatsu Shibasaki

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 25 KB
Volume: 42
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200390615

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Titelbild: Multicenter Strategy for the

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The catalytic construction of stereogenic tetrasubstituted carbon centers through the addition of carbon nucleophiles to ketones or ketoimines is very challenging, partly because of the lower reactivity of these substrates relative to aldehydes and aldoimines. [1] This task requires strong activatio