Coupling the deoxygenation of benzoic acid with the oxidation of propylene on a Co molybdate catalyst
✍ Scribed by F. Dury; S. Meixner; D. Clément; E.M. Gaigneaux
- Book ID
- 108211521
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 513 KB
- Volume
- 237
- Category
- Article
- ISSN
- 1381-1169
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## Abstract Highly efficient formation of poly(propylene carbonate) can be achieved in the coupling of CO~2~ and propylene oxide assisted by 4‐(__N,N__‐dimethylamino)pyridine (DMAP) and catalyzed with salen chromium(III) chloride by using DMAP/Cr ratios of less than 2. Under these conditions a poss
The role of the carboxylic acid as co-catalyst in metalloporphyrin catalytic hydrogen peroxide oxidations is discussed, taking into account its dependence on the ratio relatively to the catalyst. The catalytic efficiency and stability of the catalyst in the presence of an excess of carboxylic acid s