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A mechanistic study on the stereoregular polymerization of propylene oxide by the Pruitt-Baggett catalyst

✍ Scribed by F. Takrouri; K. Alyürük


Book ID
107847015
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
698 KB
Volume
35
Category
Article
ISSN
0032-3861

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A mechanistic study on the polymerizatio
✍ Osman Yilmaz; Ali Usanmaz; Kemal Alyürük 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 308 KB

The mechanism of the polymerization of n-butyl isocyanate by the Pruitt-Baggett adduct (PBA) was studied; on the basis of the experimental evidences, a coordinated mechanism was proposed and verified. This mechanism considers a monatomic active site, which is the Fe atom of PBA with Lewis acid chara