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Coupling of allylic alcohol epoxides with sulfur-stabilized allylic anions

✍ Scribed by Marshall, James A.; Andrews, Robert C.

Book ID
120078706
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
739 KB
Volume
50
Category
Article
ISSN
0022-3263

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## Abstract **Regioselective, stereoselective**: The convergent coupling of allylic alcohols with imines to deliver stereodefined homoallylic amines is described (see scheme). The process proceeds with net allylic transposition without the intermediacy of allylic organometallic reagents. Two stereo