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Coupled cluster calculations for the SN2 reaction Cl− + CH3Br → ClCH3 + Br−

✍ Scribed by Stefan Schmatz; Peter Botschwina; Hermann Stoll


Book ID
104432051
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
56 KB
Volume
201
Category
Article
ISSN
1387-3806

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## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m