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Temperature dependence of the kinetic isotope effect for a gas-phase SN2 reaction: Cl- + CH3Br

โœ Scribed by Viggiano, A. A.; Paschkewitz, John; Morris, Robert A.; Paulson, John F.; Gonzalez-Lafont, Angels; Truhlar, Donald G.


Book ID
126144804
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
284 KB
Volume
113
Category
Article
ISSN
0002-7863

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To obtain essential information on the reaction dynamics for the prototype gas-phase S 2 reaction Cl y q CH Cl ยช ClCH q Cl y , the characteristic N 3 3 features of the potential energy surface in the local region around the reaction path were examined by the reaction path Hamiltonian constructed wit