Photosynthetic reaction centers, isolated and purified from the facultative phototrophic bacterium Chloroflexus auranfiacus, were immobilized in optically transparent lipidic cubic phases composed of 42% (w/w) l-palmitoyl-2-hydroxy-sn-glycero-3-phosphocholine and 58% (w/w) water. The immobilized pho
Correlation of structural and spectroscopic properties of a photosynthetic reaction center
β Scribed by W. Zinth; E.W. Knapp; S.F. Fischer; W. Kaiser; J. Deisenhofer; H. Michel
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 339 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Polarized spectra of absorption and light-induced absorbance changes are presented for the crysrallized rcacilon centers ol
Rhodopseudomonas uiridis
We find Lhar a model based on extended dipole inleractnon between rll six pigments is capable or interpreting delailed features such as Lhe ccmtribulions from the individual plgmenls LO the various absorplion peaks. Even though the pigmen& are arranged in approximate C, symmerry. tie optical spectra together with the calculalions reflect deviations from ibis symmetry, which may be imporlanl in underslanding the electron pathway
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Films with alternating layers of thylakoid membrane from the cyanobacterium Spirulina platensis and the positively charged polyion poly(ethylenimine) (PEI) were prepared by means of alternate electrostatic layer-by-layer assembly. The thylakoid membrane/PEI bilayers were functionally and structurall
Bond lengths, quadrupole coupling constants, chemical shifts and vibrational frequencies are important probes of hydrogen bonding. This was previously demonstrated for liquid N-methylacetamide (NMA) showing that cooperativity and non-additive contributions of hydrogen bonds play a significant role.
This paper presents the synthesis and characterization by mass spectrometry and NMR spectroscopy of [2-13 C]-and [3-13 C]ubiquinone-0 and of [5-13 C]-and [6-13 C]ubiquinone-10. A scheme based on the synthetic approach to [5-13 C]ubiquinone-10 has been worked out for the synthesis of ubiquinones 13 C