Correlation between thermal electron transfer in solution and photoelectron emission
β Scribed by Paul Delahay
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 362 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The photoelectron emission threshold energy E, of a solute is related to its photoosidation threshoId energy IS by the following correlation: Et = fs -P\_ -170, where Vo is the solvent conduction band depth and P\_ = -(e\*/2r)(l -DLi) is the polarization energy of the mobile electron with r derived
Recent experimental data concerning the rate constants for electron transfer reactions of organic systems in aqueous solutions and their equilibrium constants is examined for possible correlation. The data is correlated quite well by the
## In micellar sodium dodecylsulfate (SDS) solution ground-state charge-transfer complexes between aromatic hydrocarbons and diazonium salts can be detected by UV absorption_ The hydrocarbon fluorescence quenching occurs by both static and dynamic mechanisms and can be described by an established