✦ LIBER ✦

Correlation between the photoelectron emission and photooxidation threshold energies of a solute in the condensed phase

✍ Scribed by Thu Ba Truong

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 589 KB
Volume: 100
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87266-2

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✦ Synopsis

The photoelectron emission threshold energy E, of a solute is related to its photoosidation threshoId energy IS by the following correlation: Et = fs -P_ -170, where Vo is the solvent conduction band depth and P_ = -(e*/2r)(l -DLi) is the polarization energy of the mobile electron with r derived from a solute-solvent cage charge-transfer model. For the fist oxidation state, .A -At + e-, the Et of a soiute A differs from its gas-phase oxidation energy by 3 solute-solvent cage interaction term k&m_

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