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Photoinduced electron transfer between aromatic hydrocarbons and arene diazonium salts in micellar solutions

โœ Scribed by Hans-Joachim Timpe; G. Israel; H.G.O. Becker; Ian R. Gould; Nicholas J. Turro


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
536 KB
Volume
99
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


In micellar sodium dodecylsulfate (SDS) solution ground-state charge-transfer complexes between aromatic hydrocarbons and diazonium salts can be detected by UV absorption_ The hydrocarbon fluorescence quenching occurs by both static

and dynamic mechanisms and can be described by an established kinetic scheme.


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The electron transfer reaction between a
โœ S.M. Hubig; M.A.J. Rodgers ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 178 KB

The electron transfer reaction between anthraquinone sulfonate radicals and duroquinone has been studied in aqueous and micellar (sodium dodecyl sulfate, SDS) solution using the electron pulse radiolysis technique. The forward electron transfer rate constant decreased significantly with increasing S