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Correction. Diazotization of endo- 7-Aminomethylbicyclo[3.3.1]nonan-3-ols and endo- 7-Aminomethylbicyclo[3.3.1]non-2-ene

โœ Scribed by Wnuk, Thomas A.; Tonnis, John A.; Dolan, Michael J.; Padegimas, Stanley J.; Kovacic, Peter.

Book ID
126811817
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
151 KB
Volume
41
Category
Article
ISSN
0022-3263

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The base-induced rearrangement of endo-7
The base-induced rearrangement of endo-7,7-dimethylbicyclo[3.3.1]nonan-3-ol-9-one
โœ I. Watt ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 207 KB

We have recently described' rapid reversible 3,7-hydride transfer in the alkoxide of exo-bicyclo[3.3.11 nonan-7-ol-3-one (1). We now report the base-induced rearrangement of the title compound (3) to anti-7,7-dimethylbicycl0[3.3.l]nonan-9-ol-3-one (4) , a process involving 3,9-hydride transfer withi