Correction. Complexes between Pyridine-2-aldehydel2'-pyridylhydrazone and the Platinum Metals. I. Rhodium
β Scribed by Bell, Colin; Rose, David
- Book ID
- 125901806
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 129 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
Rhodium(I), iridium(I), palladium(lI) and platinum(II) complexes of the phosphinoamide ligands, Ph2PCH2CONHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized by using conductivity data, i.r., 1H and31P(H) n.m.r, spectral data. Reaction of the ligands with MCI(PPh3) 3 and MCI(CO)(PPh
Reactions of [RhClL] (L,=diolefin or (CO)(PPh,)) with the deprotonated form of the ligand 3,5bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh&)(bpt)]. Cationic, mono-and dinuclear species of formulae [Rh&.)(Hbpt)]+, [{Rhb}\*(bpt)]+ and [{Rh&.}@bpt)]\*+, where b=diolefi